Synthesis of an ionic liquid with an iron coordination cation.
نویسندگان
چکیده
An iron-based ionic liquid, Fe((OHCH(2)CH(2))(2)NH)(6)(CF(3)SO(3))(3), is synthesized in a single-step complexation reaction. Infrared and Raman data suggest NH(CH(2)CH(2)OH)(2) primarily coordinates to Fe(iii) through alcohol groups. The compound has T(g) and T(d) values of -64 degrees C and 260 degrees C, respectively. Cyclic voltammetry reveals quasi-reversible Fe(iii)/Fe(ii) reduction waves.
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عنوان ژورنال:
- Dalton transactions
دوره 39 37 شماره
صفحات -
تاریخ انتشار 2010